KOAc-promoted alkynylation of α-C–H bonds of ethers with alkynyl bromides under transition-metal-free conditions-Reference-Cited by-同舟云学术

KOAc-promoted alkynylation of α-C–H bonds of ethers with alkynyl bromides under transition-metal-free conditions

Published:2014 Issue:18 Volume:12 Page:2969-2978
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Jiajun¹²³,Li Pinhua¹²³,Wang Lei¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Huaibei Normal University

3. Huaibei, P R China

4. State Key Laboratory of Organometallic Chemistry

5. Shanghai Institute of Organic Chemistry

Abstract

KOAc-promoted α-position C–H activation and alkynylation of ethers with alkynyl bromides to 2-alkynyl ethers was developed under transition-metal-free conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00002A

Reference84 articles.

1. C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

2. Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

3. Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

4. Direct C−H Transformation via Iron Catalysis

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