Theoretical insights into the alkaline metal M (M = Na and Cs) promotion mechanism for CO2 activation on the Cu(111) surface-Reference-Cited by-同舟云学术

Theoretical insights into the alkaline metal M (M = Na and Cs) promotion mechanism for CO2 activation on the Cu(111) surface

Published:2016 Issue:72 Volume:6 Page:67866-67874
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ou Lihui¹²³⁴,Chen Yuandao¹²³⁴,Jin Junling¹²³⁴

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Hunan University of Arts and Science

3. Changde 415000

4. China

Abstract

The promotion effect of alkaline metals for CO₂ reduction into hydrocarbons on Cu catalysts can be attributed to a reduction of the activation barrier for CO₂ dissociation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA10321A

Reference55 articles.

1. PRODUCTION OF METHANE AND ETHYLENE IN ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE AT COPPER ELECTRODE IN AQUEOUS HYDROGENCARBONATE SOLUTION

2. Electroreduction of carbon monoxide to methane and ethylene at a copper electrode in aqueous solutions at ambient temperature and pressure

3. A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper

4. Evidence for Formaldehyde, Formic Acid, and Acetaldehyde as Possible Intermediates during Electrochemical Carbon Dioxide Reduction at Copper

5. Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions

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