Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives-Reference-Cited by-同舟云学术

Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives

Published:2015 Issue:24 Volume:44 Page:11119-11128
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pedrosa Sergio¹²³⁴⁵,Vidal Fernando¹²³⁴⁵,Lee Lucia Myongwon⁶⁷⁸⁹,Vargas-Baca Ignacio⁶⁷⁸⁹,Gómez-Sal Pilar¹²³⁴⁵,Mosquera Marta E. G.¹²³⁴⁵

Affiliation:

1. Departamento de Química Orgánica y Química Inorgánica

2. Universidad de Alcalá

3. Campus Universitario

4. E-28871 Alcalá de Henares

5. Spain

6. Department of Chemistry and Chemical Biology

7. McMaster University

8. Hamilton

9. Canada

Abstract

Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η⁵-C₅Me₅)(NR)(NHR)₂]. Computational studies corroborate its charge-separated nature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01320H

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4. Structures of [(CH3)2(t-BuN)W]2(.mu.-t-BuN)2 and [((CH3)2N)2Ti]2(.mu.-t-BuN)2. A molecular orbital explanation of the existence of unsymmetrically or symmetrically bridging organoimido ligands

5. New transition metal imido chemistry with diamido-donor ligands

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