The crystal structure and magnetic properties of 3-pyridinecarboxylate-bridged Re(ii)M(ii) complexes (M = Cu, Ni, Co and Mn)-Reference-Cited by-同舟云学术

The crystal structure and magnetic properties of 3-pyridinecarboxylate-bridged Re(ii)M(ii) complexes (M = Cu, Ni, Co and Mn)

Published:2015 Issue:25 Volume:44 Page:11636-11648
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pacheco Mario¹²³⁴⁵,Cuevas Alicia¹²³⁴⁵,González-Platas Javier⁶⁷⁸⁹,Lloret Francesc¹⁰¹¹¹²⁹,Julve Miguel¹⁰¹¹¹²⁹,Kremer Carlos¹²³⁴⁵

Affiliation:

1. Cátedra de Química Inorgánica

2. Departamento Estrella Campos

3. Facultad de Química

4. Universidad de la República

5. Montevideo

6. Departamento de Física

7. Servicio de Difracción de Rayos X. Universidad de La Laguna

8. Tenerife

9. Spain

10. Instituto de Ciencia Molecular

11. Universidad de Valencia

12. 46980 Paterna

Abstract

Five novel complexes [Re^II(NO)Br₄(μ-nic)M^II(L)₂] have been prepared and fully characterized. The magnetic properties show the behavior of quasi magnetically isolated spin doublets with very weak antiferromagnetic interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01321F

Reference54 articles.

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3. New Paramagnetic Re(II) Compounds with Nitrile and Cyanide Ligands Prepared by Homolytic Scission of Dirhenium Complexes

4. Magnetic properties of complex d 1 and d 5 ions: crystal field model and Jahn–Teller effect

5. Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature-Independent Paramagnetism

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