The role of cation size in the ordered–disordered phase transition temperature and cation hopping mechanism based on LiCB<sub>11</sub>H<sub>12</sub>-Reference-Cited by-同舟云学术

The role of cation size in the ordered–disordered phase transition temperature and cation hopping mechanism based on LiCB₁₁H₁₂

Published:2023 Issue:10 Volume:4 Page:2269-2280
ISSN:2633-5409
Container-title:Materials Advances
language:en
Short-container-title:Mater. Adv.

Author:

Sau Kartik¹²^ORCID,Takagi Shigeyuki³^ORCID,Ikeshoji Tamio²^ORCID,Kisu Kazuaki³^ORCID,Sato Ryuhei¹^ORCID,Orimo Shin-ichi¹³^ORCID

Affiliation:

1. Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Aoba-ku, Sendai 980-8577, Japan

2. Mathematics for Advanced Materials Open Innovation Laboratory (MathAM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), c/o Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan

3. Institute for Materials Research (IMR), Tohoku University, Sendai 980-8577, Japan

Abstract

The ordered–disordered transition temperature is reduced significantly with increasing cationic sizes. A possible principle for creating better ion-conducting materials is to have smaller cations in a larger unit cell.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2023/MA/D2MA00936F

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