Analyzing mechanisms in Co(i) redox catalysis using a pattern recognition platform-Reference-Cited by-同舟云学术

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Analyzing mechanisms in Co(i) redox catalysis using a pattern recognition platform

Published:2021 Issue:13 Volume:12 Page:4771-4778
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tang Tianhua¹²³⁴,Sandford Christopher¹²³⁴^ORCID,Minteer Shelley D.¹²³⁴^ORCID,Sigman Matthew S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Utah

3. Salt Lake City

4. USA

Abstract

Through kinetic studies combining electroanalytical techniques with multivariable linear-regression (MLR) analysis, a pattern recognition platform is established to determine the electron-transfer mechanism (inner-sphere or outer-sphere) of an electrochemical reduction of benzyl bromides, mediated by different cobalt complexes.

Funder

National Science Foundation

University of Utah

National Institutes of Health

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06725C

Reference58 articles.

1. Homogeneous redox catalysis of electrochemical reactions electron transfers followed by a very fast chemical step

2. Indirect Electroorganic Syntheses—A Modern Chapter of Organic Electrochemistry[New Synthetic Methods(59)]

3. Fast kinetics by means of direct and indirect electrochemical techniques

4. Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

5. Redox catalysis in organic electrosynthesis: basic principles and recent developments

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