Establishing linear-free-energy relationships for the quadricyclane-to-norbornadiene reaction-Reference-Cited by-同舟云学术

Establishing linear-free-energy relationships for the quadricyclane-to-norbornadiene reaction

Published:2020 Issue:11 Volume:18 Page:2113-2119
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Mansø Mads¹²³⁴⁵^ORCID,Petersen Anne Ugleholdt¹²³⁴^ORCID,Moth-Poulsen Kasper⁵⁶⁷⁸^ORCID,Nielsen Mogens Brøndsted¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. DK-2100 Copenhagen Ø

4. Denmark

5. Department of Chemistry and Chemical Engineering

6. Chalmers University of Technology

7. 412 96 Gothenburg

8. Sweden

Abstract

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.

Funder

Københavns Universitet

Knut och Alice Wallenbergs Stiftelse

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00147C

Reference28 articles.

1. Low Molecular Weight Norbornadiene Derivatives for Molecular Solar-Thermal Energy Storage

2. Liquid Norbornadiene Photoswitches for Solar Energy Storage

3. Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times

4. Norbornadiene-Based Photoswitches with Exceptional Combination of Solar Spectrum Match and Long-Term Energy Storage

5. Heteroaryl-linked norbornadiene dimers with redshifted absorptions

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