Copper-ion assisted photochemical vapor generation of bromide and bromate
Author:
Affiliation:
1. Universidade Federal de Santa Catarina (UFSC)
2. Departamento de Química
3. Florianópolis
4. Brazil
5. National Research Council of Canada
6. Metrology
7. Inorganic Chemical Metrology
8. Ottawa
9. Canada
Abstract
Efficient photochemical vapor generation of CH3Br from bromide and bromate using a medium consisting of 2% acetic acid and 10 mg L−1 Cu2+ is demonstrated. Mechanisms involving a Cu–Br complex are discussed.
Funder
Conselho Nacional de Desenvolvimento Científico e Tecnológico
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Publisher
Royal Society of Chemistry (RSC)
Subject
Spectroscopy,Analytical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/JA/D1JA00094B
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