Electrochemical hydrogen evolution reaction catalysed by a dinuclear cobalt complex with doubly N-confused hexaphyrin

Author:

Takada Risa1,Nakazono Takashi2ORCID,Nishimura Taiyo1,Shiga Takuya3ORCID,Nihei Masayuki3,Yamada Yusuke24ORCID,Wada Tohru1ORCID

Affiliation:

1. Department of Chemistry, College of Science, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan

2. Research Center for Artificial Photosynthesis (ReCAP), Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

3. Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Ibaraki, Japan

4. Department of Chemistry and Bioengineering, Graduate School of Engineering, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

Abstract

A dinuclear cobalt complex with a doubly N-confused hexaphyrin, Co2DNCH, showed high catalytic activity for electrochemical hydrogen reduction due to the wide π-conjugated system of DNCH.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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