Conformational composition, molecular structure and decomposition of difluorophosphoryl azide in the gas phase-Reference-Cited by-同舟云学术

Conformational composition, molecular structure and decomposition of difluorophosphoryl azide in the gas phase

Published:2015 Issue:14 Volume:17 Page:8784-8791
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Zhuang¹²³⁴⁵,Li Hongmin¹²³⁴⁵,Zhu Bifeng¹²³⁴⁵,Zeng Xiaoqing¹²³⁴⁵,Hayes Stuart A.⁶⁷⁸⁹,Mitzel Norbert W.⁶⁷⁸⁹,Beckers Helmut¹⁰¹¹¹²⁹,Berger Raphael J. F.¹³¹⁴¹⁵¹⁶

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Materials Science

3. Soochow University

4. 215123 Suzhou

5. China

6. Lehrstuhl für Anorganische Chemie und Strukturchemie

7. Centre for Molecular Materials CM2

8. D-33615 Bielefeld

9. Germany

10. Institut für Chemie und Biochemie

11. Freie Universität Berlin

12. 14195 Berlin

13. Materialchemie

14. Paris-Lodron-Universität Salzburg

15. A-5020 Salzburg

16. Austria

Abstract

Difluorophosphoryl azide F₂P(O)N₃ has one dominating conformer in the gas phase at ambient temperature. It decomposes upon flash vacuum pyrolysis to the hitherto unknown nitrene F₂P(O)N.

Funder

Deutsche Forschungsgemeinschaft

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP00850F

Reference66 articles.

1. S. Bräse and K.Banert, Organic Azides: Syntheses and Applications, Wiley, Chichester, 2010

2. R. A. Moss , M. S.Platz and M. J.Jones, Reactive Intermediates, Wiley-Interscience, 2004