Manganese(<scp>i</scp>)-catalyzed nucleophilic addition of C(sp<sup>3</sup>)–H bonds to aldehydes-Reference-Cited by-同舟云学术

Manganese(i)-catalyzed nucleophilic addition of C(sp³)–H bonds to aldehydes

Published:2024 Issue:38 Volume:60 Page:5066-5069
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Hongxin¹,Tang Tingyu¹,Li Bin¹^ORCID,Wang Baiquan¹²^ORCID

Affiliation:

1. State Key Laboratory of Elemento-Organic Chemistry and Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 300071, People's Republic of China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, People's Republic of China

Abstract

Manganese(i)-catalyzed direct nucleophilic addition reaction of C(sp3)–H bonds to aromatic aldehydes has been developed. This is the first example of manganese(i)-catalyzed C(sp3)–H bond activation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Tianjin Municipality

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01338G

Reference42 articles.

1. Manganese-Mediated C-C Bond Formation via C-H Activation: From Stoichiometry to Catalysis

2. Manganese-Catalyzed C–H Activation

3. Inert C–H Bond Transformations Enabled by Organometallic Manganese Catalysis

4. Recent advances and perspectives in manganese-catalyzed C–H activation

5. Manganese-catalyzed hydroarylation of multiple bonds

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