Synthesis of (1-silyl)allylboronates by KO<i>t</i>Bu-catalyzed ring-opening <i>gem</i>-silylborylation of cyclopropenes-Reference-Cited by-同舟云学术

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Synthesis of (1-silyl)allylboronates by KOtBu-catalyzed ring-opening gem-silylborylation of cyclopropenes

Published:2024 Issue:54 Volume:60 Page:6921-6924
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fujii Ikuya¹²,Hirata Haruka¹,Moniwa Hirokazu¹,Shintani Ryo¹²^ORCID

Affiliation:

1. Division of Chemistry, Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan

Abstract

A KOtBu-catalyzed ring-opening gem-silylborylation of cyclopropenes with silylboronates has been developed for the synthesis of (1-silyl)allylboronates, a useful class of compounds in organic synthesis.

Funder

Japan Science and Technology Agency

Japan Society for the Promotion of Science

Toray Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01336K

Reference50 articles.

1. Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

2. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

3. Selective reactions using allylic metals

4. Diastereogenic Addition of Crotylmetal Compounds to Aldehydes

5. Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis

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