Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- vs. exohedral geometry-Reference-Cited by-同舟云学术

Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- vs. exohedral geometry

Published:2022 Issue:3 Volume:24 Page:1447-1455
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Minamikawa Kento¹,Sarugaku Shun¹,Arakawa Masashi¹^ORCID,Terasaki Akira¹^ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Cationic and anionic AgNM+/− (M = Sc–Ni) clusters are explored to examine the electron-counting rule. Among 18-valence-electron clusters, endohedrally doped ones are stable due to superatomic electron-shell closure involving delocalized 3d electrons.

Funder

Sumitomo Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04197E

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1. Electronic Shell Structure and Abundances of Sodium Clusters

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