Construction of diverse polycyclic N-heterocycles <i>via</i> cascade allylic amination/Diels

Construction of diverse polycyclic N-heterocycles via cascade allylic amination/Diels–Alder reaction

Published:2022 Issue:95 Volume:58 Page:13258-13261
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yang Zhenkun¹,Xie Hongling¹,Tang Luning¹,Sun Jianwei¹²^ORCID,Han Zhengyu¹,Huang Hai¹^ORCID

Affiliation:

1. Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China

2. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China

Abstract

An efficient cascade approach for the construction of nitrogen-containing polycyclic compounds from amines tethered with an alkenyl (or alkynyl) group and divinyl carbonates is described.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05208C

Reference49 articles.

1. Domino Reactions in Organic Synthesis

2. Concurrent Tandem Catalysis

3. Cascade Reactions in Total Synthesis

4. Constructing molecular complexity and diversity: total synthesis of natural products of biological and medicinal importance

5. The Type 2 Intramolecular Diels-Alder Reaction: Synthesis and Chemistry of Bridgehead Alkenes

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