A photoinduced mixed valence photoswitch-Reference-Cited by-同舟云学术

A photoinduced mixed valence photoswitch

Published:2022 Issue:24 Volume:24 Page:15121-15128
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cotic Agustina¹²^ORCID,Cerfontaine Simon³^ORCID,Slep Leonardo D.¹²^ORCID,Elias Benjamin³^ORCID,Troian-Gautier Ludovic³^ORCID,Cadranel Alejandro¹²⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina

2. CONICET – Universidad de Buenos Aires, Instituto de Química-Física de Materiales, Medio Ambiente y Energía (INQUIMAE), Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina

3. Université catholique de Louvain (UCLouvain), Institut de la Matière Condensée et des Nanosciences (IMCN), Molecular Chemistry, Materials and Catalysis (MOST), Place Louis Pasteur 1, bte L4.01.02, 1348 Louvain-la-Neuve, Belgium

4. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Physical Chemistry I, Egerlandstr. 3, 91058, Erlangen, Germany

5. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Interdisciplinary Center for Molecular Materials, Egerlandstr. 3, 91058, Erlangen, Germany

Abstract

The ground and photoinduced mixed valence states of a dinuclear ruthenium(ii) complex were investigated using ultrafast transient absorption spectroscopy, electrochemistry and DFT. A Class II excited state contrasts with a Class I ground state.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Fondo para la Investigación Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01791A

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