Chemical equilibria of aqueous ammonium–carboxylate systems in aqueous bulk, close to and at the water

Chemical equilibria of aqueous ammonium–carboxylate systems in aqueous bulk, close to and at the water–air interface

Published:2019 Issue:23 Volume:21 Page:12434-12445
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Blanco Yina Salamanca¹²³⁴,Topel Önder¹²³⁴^ORCID,Bajnóczi Éva G.¹²³⁴^ORCID,Werner Josephina¹²³⁴⁵^ORCID,Björneholm Olle⁵⁶⁷⁴,Persson Ingmar¹²³⁴^ORCID

Affiliation:

1. Department of Molecular Sciences

2. Swedish University of Agricultural Sciences

3. SE-750 07 Uppsala

4. Sweden

5. Department of Physics and Astronomy

6. Uppsala University

7. SE-751 20 Uppsala

Abstract

XPS studies have used to study the speciation and the relative position of alkyl carboxylic acids and conjugated carboxylates relative to the water air–air interface. The transport of ammonia and small carboxylic acids from water to air show that equilibria between the aqueous bulk and the surface region establish fast.

Funder

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02449B

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