Bio-inspired asymmetric aldehyde arylations catalyzed by rhodium-cyclodextrin self-inclusion complexes

Author:

Tsuda Susumu1ORCID,Asahi Kaoru2,Takahashi Ryota2,Yamauchi Hiroki2,Ueda Ryoji2,Iwasaki Takanori23ORCID,Fujiwara Shin-ichi1,Kambe Nobuaki2

Affiliation:

1. Department of Chemistry, Osaka Dental University, Hirakata, Osaka 573-1121, Japan

2. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

3. Department of Chemistry and Biotechnology, Graduate School of Engineering, University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

The high enantioselective arylation was pseudo-biologically accererated by self-inclusion of the Rh complex bearing a γ-cyclodextrin.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference53 articles.

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5. J. A.Gillespie , E.Zuidema , P. W. N. M.van Leeuwen and P. C. J.Kamer , in Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis , ed. P. C. J. Kamer and P. W. N. M. van Leeuwen , Wiley , Chichester , 2012 , pp. 1–26

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Halogen‐Substituted Mesoionic‐Carbene/Palladium Complexes for Catalytic Arylation of Aldehydes;Asian Journal of Organic Chemistry;2023-04-03

2. Bio-inspired catalysis;Comprehensive Inorganic Chemistry III;2023

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