Experimental and computational studies on pseudotetrahedral nickel(<scp>ii</scp>)-(<i>S</i> or <i>R</i>)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal-Reference-Cited by-同舟云学术

Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal

Published:2023 Issue:3 Volume:25 Page:365-377
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Saadati Arezoo¹,Amiri Rudbari Hadi¹^ORCID,Aryaeifar Mahnaz¹,Blacque Olivier²^ORCID,Correia Isabel³^ORCID,Islam Mohammad Khairul⁴^ORCID,Woschko Dennis⁵^ORCID,Haj Hassani Sohi Takin⁵^ORCID,Janiak Christoph⁵^ORCID,Enamullah Mohammed⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran

2. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland

3. Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal

4. Department of Chemistry, Jahangirnagar University, Dhaka 1342, Bangladesh

5. Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany

Abstract

Synthesis of pseudotetrahedral bis[(S or R)-N-1-(phenyl)ethyl-(2,4-dihalogen-salicylaldiminato-κ2N,O)]-Δ/Λ-nickel(ii), Δ/Λ-Ni(S or R)L1–3 with Δ- or Λ-chirality induction at-metal.

Funder

Alexander von Humboldt-Stiftung

University of Isfahan

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D2CE01311H

Reference58 articles.

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3. Stereogenic metal centres – from Werner to supramolecular chemistry

4. Tentative proposals for nomenclature of absolute configurations concerned with six-coordinated complexes based on the octahedron

5. Predetermined Chirality at Metal Centers

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