Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal

Author:

Saadati Arezoo1,Amiri Rudbari Hadi1ORCID,Aryaeifar Mahnaz1,Blacque Olivier2ORCID,Correia Isabel3ORCID,Islam Mohammad Khairul4ORCID,Woschko Dennis5ORCID,Haj Hassani Sohi Takin5ORCID,Janiak Christoph5ORCID,Enamullah Mohammed4ORCID

Affiliation:

1. Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran

2. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland

3. Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal

4. Department of Chemistry, Jahangirnagar University, Dhaka 1342, Bangladesh

5. Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany

Abstract

Synthesis of pseudotetrahedral bis[(S or R)-N-1-(phenyl)ethyl-(2,4-dihalogen-salicylaldiminato-κ2N,O)]-Δ/Λ-nickel(ii), Δ/Λ-Ni(S or R)L1–3 with Δ- or Λ-chirality induction at-metal.

Funder

Alexander von Humboldt-Stiftung

University of Isfahan

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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