Pillared MOFs: structure and ring opening polymerization of cyclic esters

Author:

Gong Yi1,Chen Fei1,Beamish-Cook Jethro1,Elsegood Mark R. J.2ORCID,Derbyshire Max2,Rowe Oliver3,Redshaw Carl1ORCID

Affiliation:

1. Department of Chemistry, University of Hull, Hull, HU6 7RX, UK

2. Chemistry Department, Loughborough University, Loughborough, Leicestershire, LE11 3TU, UK

3. School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK

Abstract

Pillared 2- and 3D MOFs have been isolated from reactions of 5-aminoisophthalic acid, 4,4′-bipyridyls and metal (Zn, Co, Mn, Cd) nitrate salts. Their ability to act as catalysts for the ROP of ε-caprolactone and δ-valerolactone has been investigated.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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