Solvent effect on simple and high yield synthesis of polydichlorophosphazene precursor Cl3PNSiMe3-Reference-Cited by-同舟云学术

Solvent effect on simple and high yield synthesis of polydichlorophosphazene precursor Cl3PNSiMe3

Published:2021 Issue:41 Volume:45 Page:19364-19372
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Çelebi Elif Büşra¹^ORCID,Hacıvelioğlu Ferda¹²³^ORCID

Affiliation:

1. Department of Chemistry, Gebze Technical University, 41400, Gebze, Kocaeli, Turkey

2. University of Glasgow, School of Chemistry, G12 8QQ, Glasgow, UK

3. Heges Kimya Ltd, GTUTeknopark, No. 42/1, Gebze, Kocaeli, Turkey

Abstract

The effect of solvent polarity on the reaction of PCl5 with (Me3Si)2NH has been investigated and it is found that nonpolar solvents promote the formation of Cl3PNSiMe3, whereas the more polar chloroform gives unusual phosphazenes at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ03721H

Reference44 articles.

1. Polyphosphazenes: Phosphorus in Inorganic–Organic Polymers

2. S. P.Nukavarapu , S. G.Kumbar , H. R.Allcock and C. T.Laurencin , in Polyphosphazenes for Biomedical Applications , ed. A. K. Andrianov , John Wiley & Sons Inc , 2009 , ch. 8, pp. 119–151 10.1002/9780470478882

3. Recent research progress on polyphosphazene-based drug delivery systems

4. Recent advances in experimental polyphosphazene adjuvants and their mechanisms of action

5. In Vivo and In Vitro Potency of Polyphosphazene Immunoadjuvants with Hepatitis C Virus Antigen and the Role of Their Supramolecular Assembly

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Theory-driven design of phosphazene-based porous polymer beads for enhanced iodine adsorption;Separation and Purification Technology;2024-10

2. Phosphazenes;Organophosphorus Chemistry;2024-02-21

3. Water‐soluble Polypyrrole‐Polybis(4‐oxy benzene sulfonic acid)phosphazene Composites and Investigation of Their Performance as Cathode Binder in Li‐ion Batteries;ChemSusChem;2024-02-20

4. A polyphosphazene elastomer containing 2,2,2-trifluoroethoxy groups as a dielectric in electrically responsive soft actuators;Journal of Materials Chemistry C;2024

5. Poly(3,4-ethylenedioxythiophene)/poly(bis(4-phenoxysulfonic acid)phosphazene) conductive composites: an alternative interfacial layer to PEDOT : PSS;Journal of Materials Chemistry C;2024