Porphyrin bearing phenothiazine pincers as hosts for fullerene binding via concave–convex complementarity: synthesis and complexation study

Author:

Jain Kanika1,Duvva Naresh2ORCID,Roy Tapta Kanchan3ORCID,Giribabu Lingamallu24ORCID,Chitta Raghu15ORCID

Affiliation:

1. Department of Chemistry, School of Chemical Sciences & Pharmacy, Central University of Rajasthan, Bandarsindri, Tehsil: Kishanhgarh, Dist, Ajmer, Rajasthan 305817, India

2. Polymers and Functional Materials Division, CSIR - Indian Institute of Chemical Technology, Hyderabad, Telangana 500007, India

3. Department of Chemistry and Chemical Sciences, Central University of Jammu, Rahya-Suchani (Bagla), Dist, Samba, Jammu and Kashmir 181143, India

4. Academy of Scientific and Innovative Research, Ghazianbad 201002, India

5. Department of Chemistry, National Institute of Technology Warangal, Hanamkonda, Dist, Hanamkonda, Telangana 506004, India

Abstract

Free base porphyrin hosts, m-(PTZ)4-H2P and p-(PTZ)4-H2P, tethered with four phenothiazine moieties at the meso-position via a flexible ethoxy phenyl linker were synthesized and used for the selective complexation of fullerenes, C60 and C70.

Funder

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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