Regiospecific and highly stereoselective synthesis of β-amino (Z)-enylphosphonates via β-hydrogen migration reaction of dialkyl α-diazophosphonates catalyzed by AgOTf-Reference-Cited by-同舟云学术

Regiospecific and highly stereoselective synthesis of β-amino (Z)-enylphosphonates via β-hydrogen migration reaction of dialkyl α-diazophosphonates catalyzed by AgOTf

Published:2014 Issue:41 Volume:4 Page:21492-21496
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Cai Yan¹²³⁴³,Ge Haihong¹²³⁴³,Yu Chengbin¹²³⁴³,Sun Weize¹²³⁴³,Zhan Junchen¹²³⁴³,Miao Zhiwei¹²³⁴³

Affiliation:

1. State Key Laboratory of Elemento-Organic Chemistry

2. Institute of Elemento-Organic Chemistry

3. Nankai University

4. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

Abstract

The diazo decomposition of dialkyl α-diazophosphonates in the presence of AgOTf provides an efficient one-step route to a variety of β-amino (Z)-enylphosphonates in good yields with complete control over regio- and stereochemistry.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA02520B

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