μ3-Oxo stabilized by three metal cations is a sufficient nucleophile for enzymatic hydrolysis of phosphate monoesters
Author:
Affiliation:
1. Key Laboratory of Cluster Science of Ministry of Education
2. Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials
3. School of Chemistry
4. Beijing Institute of Technology
5. Beijing 100081
Abstract
A novel μ3-oxo stabilized by three cations is demonstrated to be a sufficient nucleophile in the hydrolysis of phosphate esters.
Funder
Beijing Nova Program
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03899E
Reference56 articles.
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2. Monomeric metaphosphates
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