Insertion of carbon monoxide into an aldehyde CO double bond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex-Reference-Cited by-同舟云学术

Insertion of carbon monoxide into an aldehyde CO double bond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex

Published:2014 Issue:37 Volume:4 Page:19068-19071
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Kanno Yuto¹²³⁴,Komuro Takashi¹²³⁴,Tobita Hiromi¹²³⁴

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578, Japan

Abstract

An (η³-α-silabenzyl)carbonylmolybdenum complex reacted with alkylaldehyde to give an η³-oxaallyl complex through CO insertion into a metallacycle C–O bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA02308K

Reference21 articles.

1. C1 Chemistry: potential and developments

2. H. M. Colquhoun , D. J.Thompson and M. V.Twigg , in Carbonylation: Direct Synthesis of Carbonyl Compounds , Plenum Press , New York , 1991

3. Catalytic Conversion of Aldehydes into Higher ?-Siloxy Aldehydes by Hydrosilane and Carbon Monoxide

4. The Co2(CO)8/Ph3P-Catalyzed Reaction of Aldehydes with Hydrosilane and Carbon Monoxide

5. Rhodium-catalyzed silylformylation of aldehydes: a mild and efficient catalytic route to .alpha.-silyloxyaldehydes

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. η3-Allyl carbonyl complexes of group 6 metals: Structural aspects, isomerism, dynamic behaviour and reactivity;Coordination Chemistry Reviews;2017-03

2. Theoretical prediction on CO insertion reactions through the anionic complex [ClMg(η 2 -O 2 C] − as a catalyst;Computational and Theoretical Chemistry;2017-02