Tuning the Mn valence state in new Ca0.66Mn2−xAlxO4 (x ≤ 0.4) oxides: impact on magnetic and redox properties-Reference-Cited by-同舟云学术

Tuning the Mn valence state in new Ca0.66Mn2−xAlxO4 (x ≤ 0.4) oxides: impact on magnetic and redox properties

Published:2016 Issue:11 Volume:45 Page:4647-4658
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lesturgez Stéphanie¹²³⁴⁵,Goglio Graziella¹²³⁴⁵,Weill François¹²³⁴⁵,N'Guyen Olivier¹²³⁴⁵,Toulemonde Olivier¹²³⁴⁵,Durand Etienne¹²³⁴⁵,Hernandez Julien⁶⁷⁸⁵,Demourgues Alain¹²³⁴⁵

Affiliation:

1. CNRS

2. ICMCB

3. UPR 9048

4. F33600 Pessac

5. France

6. SOLVAY

7. Centre de Recherche et Innovation de Paris Aubervilliers

8. 93306 Aubervilliers Cedex

Abstract

Al³⁺ substitution for Mn⁴⁺/Mn³⁺ into the Ca_0.66Mn₂O₄ 1D tunnel network leads to the stabilization of an orthorhombic unit cell (SG: Pnma) with two different Mn sites attributed mainly to Mn⁴⁺ and Mn³⁺ respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02761F

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