Isolated complexes of the amino acid arginine with polyether and polyamine macrocycles, the role of proton transfer
Author:
Affiliation:
1. Department of Physical
2. Chemical and Natural Systems
3. Universidad Pablo de Olavide
4. E-41013 Seville
5. Spain
6. Radboud University
7. Institute for Molecules and Materials
8. FELIX Laboratory
9. 6525ED Nijmegen
10. The Netherlands
Abstract
Protonated arginine interacts with 12-crown-4 through the guanidinium side group. In the complex with the N-substituted analog cyclen, the dominant conformation is the result of the proton transfer from the carboxylic acid group of the amino acid to the macrocycle.
Funder
H2020 Research Infrastructures
Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP04270A
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5. Charge transfer between the PO4- groups of DNA and the arginine+ and lysine+ side chains of proteins
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