Designing luminescent diimine-Cu(i)–phosphine complexes by tuning N-ligand and counteranions: correlation of weak interactions, luminescence and THz absorption spectra

Author:

Sun Zhen-Zhou1,Zhu Ning1,Pan Xun1,Hu Fu-Zhen1,Wang Guo1,Yang Yu-Ping2,Qiu Qi-Ming3ORCID,Li Zhong-Feng1,Xin Xiu-Lan4,Liu Jian-Ming5,Li Xiao-Qi1,Jin Qiong-Hua16ORCID,Ren Zhi-Gang7ORCID,Zhou Qing-Li8

Affiliation:

1. Department of Chemistry, Capital Normal University, Beijing 100048, China

2. School of Science, Minzu University of China, Beijing 100081, China

3. School of Science, China University of Geosciences, Beijing 100083, China

4. School of Light Industry, Beijing Technology and Business University, Beijing 100048, China

5. School of Mathematical Sciences, Peking University, Beijing 100871, China

6. State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science Fuzhou, Fujian 350002, China

7. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

8. Key Laboratory of Terahertz Optoelectronics, Ministry of Education, and Beijing Advanced Innovation Center for Imaging Theory and Technology, Department of Physics, Capital Normal University, Beijing 100048, China

Abstract

π–π stacking interactions and C–H⋯X (X = O, F) interactions formed by counteranions help to enhance the rigidity of these structures and further improve their luminescence quantum yields.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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