Enhanced Raman scattering based on a ZnO/Ag nanostructured substrate: an in-depth study of the SERS mechanism

Author:

Tran Thu Trang1,Vu Xuan Hoa1ORCID,Ngo Thi Lan12,Pham Thi Thu Ha3,Nguyen Dac Dien4,Nguyen Van Dang1

Affiliation:

1. Institute of Science and Technology, TNU-University of Sciences, Tan Thinh ward, Thai Nguyen city, Vietnam

2. Graduate University of Science and Technology, Vietnam Academy of Science and Technology, Hoang Quoc Viet road, Hanoi city, Vietnam

3. Faculty of Chemistry, TNU-University of Sciences, Tan Thinh ward, Thai Nguyen city, Vietnam

4. Faculty of Occupational Safety and Health, Vietnam Trade Union University, 169 Tay Son street, Dong Da district, Ha Noi city, Vietnam

Abstract

Using Herzberg–Teller-surface selection rules in combination with the results of DFT calculations, the SERS mechanism based on the ZnO/Ag substrate has indicated a significant electromagnetic contribution versus the Ag substrate, in which charge transfer plays a pivotal role.

Funder

National Foundation for Science and Technology Development

Ministry of Education and Training

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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