Palladium-catalyzed oxidative deacetonative coupling of 4-aryl-2-methyl-3-butyn-2-ols with H-phosphonates
Author:
Affiliation:
1. The College of Chemistry and Molecular Engineering
2. Henan Key Laboratory of Chemical Biology and Organic Chemistry
3. Key Laboratory of Applied Chemistry of Henan Universities
4. Zhengzhou University
5. Zhengzhou 450052
Abstract
A new and generally practical synthesis of alkynylphosphonates through a palladium-catalyzed consecutive Sonogashira/deacetonative process using aryl bromides, 2-methyl-3-butyn-2-ol and H-phosphonates is developed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02410A
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3. Synthesis of Diethyl 1,2,3-Triazolealkylphosphonates through 1,3-Dipolar Cycloaddition of Azides with Acetylenes
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5. Asymmetric Assembly of Aromatic Rings To Produce Tetra-ortho-Substituted Axially Chiral Biaryl Phosphorus Compounds
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