Tandem vinyl insertion-/ring-opening metathesis copolymerization with ansa-6-[2-(dimesitylboryl)-phenyl]pyrid-2-ylamido zirconium complexes: role of trialkylaluminum and MAO-Reference-Cited by-同舟云学术

Tandem vinyl insertion-/ring-opening metathesis copolymerization with ansa-6-[2-(dimesitylboryl)-phenyl]pyrid-2-ylamido zirconium complexes: role of trialkylaluminum and MAO

Published:2016 Issue:10 Volume:7 Page:1987-1998
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Wang Min¹²³⁴⁵,Wang Dongren¹²³⁴⁵,Widmann Laura¹²³⁴⁵,Frey Wolfgang⁶³⁴⁵,Buchmeiser Michael R.¹²³⁴⁵

Affiliation:

1. Lehrstuhl für Makromolekulare Stoffe und Faserchemie

2. Institut für Polymerchemie

3. Universität Stuttgart

4. D-70569 Stuttgart

5. Germany

6. Institut für Organische Chemie

Abstract

Activation of Zr-bisalkyl complexes containing the η⁵-tetramethylcyclopentadienyl-6-[2-(dimesitylboryl)phenyl]pyrid-2-ylamido motif with MAO offers access to poly(ethylene)-co-poly(norbornene) with ROMP-derived sequences.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00078A

Reference72 articles.

1. Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization

2. The Search for New-Generation Olefin Polymerization Catalysts: Life beyond Metallocenes

3. Highly active metallocene catalysts for olefin polymerization