Transformation of various multicenter bondings within bicapped-square antiprismatic motifs: Z-rearrangement-Reference-Cited by-同舟云学术

Transformation of various multicenter bondings within bicapped-square antiprismatic motifs: Z-rearrangement

Published:2021 Issue:35 Volume:50 Page:12098-12106
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bakardjiev Mario¹,Holub Josef¹,Růžičková Zdeňka²,Růžička Aleš²^ORCID,Fanfrlík Jindřich³,Štíbr Bohumil¹,McKee Michael L.⁴,Hnyk Drahomír¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry of the Czech Academy of Sciences, CZ – 250 68, Husinec-Řež, Czech Republic

2. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic

3. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, CZ – 166 10, Prague 6, Czech Republic

4. Department of Chemistry and Biochemistry, Auburn University, Auburn, AL, 36849, USA

Abstract

Mutual rearrangements in the whole series of bicapped-square antiprismatic closo-C2B8H10 are reported. High-quality computations and experimentally observed thermal rearrangements disprove the earlier postulated dsd (diamond-square-diamond) scheme for these isomerizations.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04225K

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