Sulphur–sulphur, sulphur–selenium, selenium–selenium and selenium–carbon bond activation using Fe3(CO)12: an unexpected formation of an Fe2(CO)6 complex containing a μ2,κ3-C,O,Se-ligand-Reference-Cited by-同舟云学术

Sulphur–sulphur, sulphur–selenium, selenium–selenium and selenium–carbon bond activation using Fe3(CO)12: an unexpected formation of an Fe2(CO)6 complex containing a μ2,κ3-C,O,Se-ligand

Published:2019 Issue:32 Volume:43 Page:12580-12593
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Trautwein Ralf¹²³⁴,Abul-Futouh Hassan⁵⁶⁷⁸^ORCID,Görls Helmar¹²³⁴,Imhof Wolfgang⁹¹⁰¹¹⁴,Almazahreh Laith R.¹²¹³⁴,Weigand Wolfgang¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Friedrich-Schiller-Universität Jena

3. 07743 Jena

4. Germany

5. Department of Pharmacy

6. Al-Zaytoonah University of Jordan

7. Amman 11733

8. Jordan

9. Institut für Integrierte Naturwissenschaften

10. Universität Koblenz-Landau

11. D-56070 Koblenz

12. ERCOSPLAN Ingenieurbüro Anlagentechnik GmbH

13. 99096 Erfurt

Abstract

Four diiron hexacarbonyl-complexes containing dithiolato (5), diselenolato (6), selenolato-thiolato (7) and μ²,κ³-C,O,Se-ligands (8), respectively have been prepared as [FeFe]-hydrogenase mimics.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ02642H

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