Transition metal-free C–F/C–Cl/C–C cleavage of ClCF2COONa for the synthesis of heterocycles-Reference-Cited by-同舟云学术

Transition metal-free C–F/C–Cl/C–C cleavage of ClCF2COONa for the synthesis of heterocycles

Published:2019 Issue:35 Volume:17 Page:8071-8074
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yan Yizhe¹²³⁴⁵^ORCID,Cui Chang¹²³⁴⁵,Wang Jianyong⁶⁷⁸⁹,Li Shaoqing¹²³⁴⁵,Tang Lin¹⁰¹¹¹²⁹^ORCID,Liu Yanqi¹²³⁴⁵

Affiliation:

1. School of Food and Biological Engineering

2. Henan Collaborative Innovation Center of Food Production and Safety

3. Henan Key Laboratory of Cold Chain Food Quality and Safety Control

4. Zhengzhou University of Light Industry

5. Zhengzhou

6. School of Light Industry and Engineering

7. Qilu University of Technology (Shandong Academy of Sciences)

8. Jinan

9. P. R. China

10. College of Chemistry and Chemical Engineering

11. Xinyang Normal University

12. Xinyang

Abstract

ClCF₂COONa was employed as a C1 synthon for 1,3,5-triazines or quinazolinones in up to 96% yields under transition metal-free and external oxidant-free conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01641D

Reference45 articles.

1. Facile One-Pot Synthesis of N-Difluoromethyl-2-pyridone Derivatives

2. A Safe and Practical Procedure for the Difluoromethylation of Methyl 4-Hydroxy-3-iodobenzoate

3. S-, N-, and Se-Difluoromethylation Using Sodium Chlorodifluoroacetate

4. Use of fluoroform as a source of difluorocarbene in the synthesis of N -CF 2 H heterocycles and difluoromethoxypyridines

5. Difluoromethylation of parent azoles

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