Chiral bisphosphine ligands based on quinoline oligoamide foldamers: application in asymmetric hydrogenation

Author:

Zheng Lu12345,Zheng Dan6784,Wang Yanru6784,Yu Chengyuan6784,Zhang Kun12345,Jiang Hua12345ORCID

Affiliation:

1. School of Biotechnology and Health Sciences

2. Wuyi University

3. Jiangmen

4. China

5. International Healthcare Innovation Institute (Jiangmen)

6. College of Chemistry

7. Beijing Normal University

8. Beijing

Abstract

Single-handed quinoline oligoamide foldamer-based bisphosphine ligands that can coordinate with Rh(cod)2BF4 were used as a platform in asymmetric hydrogenation.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference32 articles.

1. I. Huc and H.Jiang , Organic Foldamers and Helices , in Supramolecular Chemistry: From Molecules to Nanomaterials , ed. P. A. Gale and J. W. Steed , John Wiley & Sons Ltd. , Chichester, UK , 2012 , pp. 2183–2206

2. DNA-based asymmetric catalysis

3. Artificial metalloenzymes as selective catalysts in aqueous media

4. Remote Substituent Effects and Regioselective Enhancement of Electrophilic Substitutions in Helical Aromatic Oligoamides

5. Folding Directed N-Oxidation of Oligopyridine−Dicarboxamide Strands and Hybridization of Oxidized Oligomers

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