The non-dominance of counterions in charge-asymmetric electrolytes: non-monotonic precedence of electrostatic screening and local inversion of the electric field by multivalent coions-Reference-Cited by-同舟云学术

The non-dominance of counterions in charge-asymmetric electrolytes: non-monotonic precedence of electrostatic screening and local inversion of the electric field by multivalent coions

Published:2016 Issue:31 Volume:18 Page:21852-21864
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guerrero-García Guillermo Iván¹²³^ORCID,González-Tovar Enrique⁴²³,Quesada-Pérez Manuel⁵⁶⁷⁸⁹,Martín-Molina Alberto¹⁰¹¹¹²¹³¹⁴

Affiliation:

1. CONACYT – Instituto de Física de la Universidad Autónoma de San Luis Potosí

2. 78000 San Luis Potosí

3. Mexico

4. Instituto de Física de la Universidad Autónoma de San Luis Potosí

5. Departamento de Física

6. Universidad de Jaén

7. Escuela Politécnica Superior de Linares

8. 23700 Linares

9. Spain

10. Grupo de Física de Fluidos y Biocoloides

11. Departamento de Física Aplicada

12. Facultad de Ciencias

13. Universidad de Granada

14. 18071 Granada

Abstract

The relevance of multivalent coions in the electrical double layer of charged colloids containing only monovalent counterions at high electrolyte concentrations is evidenced.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03483G

Reference63 articles.

1. Hypernetted chain approximation for the distribution of ions around a cylindrical electrode. II. Numerical solution for a model cylindrical polyelectrolyte

2. Density-functional theory of spherical electric double layers and ζ potentials of colloidal particles in restricted-primitive-model electrolyte solutions

3. The electrical double layer for a fully asymmetric electrolyte around a spherical colloid: An integral equation study

4. Comparison of density functional and modified Poisson-Boltzmann structural properties for a spherical double layer

5. Simulational and theoretical study of the spherical electrical double layer for a size-asymmetric electrolyte: The case of big coions

Cited by 18 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Nonmonotonic electrophoretic mobility of rodlike polyelectrolytes by multivalent coions in added salt;Physical Review E;2024-01-11

2. Theoretical description of the electrical double layer for a mixture of n ionic species with arbitrary size and charge asymmetries. I. Spherical geometry;The Journal of Chemical Physics;2023-06-09

3. Charge asymmetric electrolytes around a rigid cylindrical polyelectrolyte: A generalization of the capacitive compactness;Journal of Molecular Liquids;2022-12

4. Effect of hydrodynamic slip on the electrophoresis of hydrophobic spherical particles in a solution of general electrolytes;Colloid and Polymer Science;2022-09-21

5. On the theory of electrolytes: correlations, excluded volume and multiple-boundaries;Physics and Chemistry of Liquids;2022-06-12