New chloramphenicol Schiff base ligands for the titanium-mediated asymmetric aldol reaction of α,β-unsaturated aldehydes with diketene: a short synthesis of atorvastatin calcium
Author:
Affiliation:
1. Department of Chemistry
2. Fudan University
3. Shanghai 200433
4. People's Republic of China
Abstract
Several novel chiral Schiff base ligands were prepared from a commercially available chloramphenicol base and applied to the titanium-mediated asymmetric aldol reaction of diketene with various α,β-unsaturated aldehydes.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA15304F
Reference36 articles.
1. Novel enantioselective reaction of diketene with aldehydes promoted by chiral Schiff base–titanium alkoxide complex
2. The Catalytic Asymmetric Aldol Reaction
3. Homogeneous Catalysis. Mechanisms of the Catalytic Mukaiyama Aldol and Sakurai Allylation Reactions
4. Novel cationic titanium(IV) Lewis acids and their use in asymmetric aldol reactions
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