BINOL-Al catalysed asymmetric cyclization and amplification: preparation of optically active menthol analogs
Author:
Affiliation:
1. Takasago International Corporation
2. Hiratsuka City
3. Japan
4. Department of Applied Chemistry and Biotechnology
5. Graduate School of Engineering
6. Chiba University
7. Chiba 263-8522
Abstract
We report a highly selective asymmetric ring-closing ene reaction catalyzed by chiral aluminum complexes. Asymmetric amplification of this reaction was investigated by varying the ee of the BINOL employed in the catalyst.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00433K
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