Ligand-free copper-catalyzed borylative defluorination: access to gem-difluoroallyl boronic acid derivatives
Author:
Affiliation:
1. Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, USA
Abstract
Funder
National Science Foundation
Virginia Polytechnic Institute and State University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB01533H
Reference43 articles.
1. Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis
2. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
3. Catalytic enantioselective transformations of borylated substrates: Preparation and synthetic applications of chiral alkylboronates
4. Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides
5. γ-Selective Cross-coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/D-t-BPF Complex
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1. Metal‐Free Defluoroborylation of 3,3‐Difluoropropenes;European Journal of Organic Chemistry;2023-09-27
2. Cu(I)‐Catalyzed Enantioselective γ‐Boryl Substitution of Trifluoromethyl‐ and Silyl‐Substituted Alkenes;European Journal of Organic Chemistry;2022-08-16
3. Enantioselective Copper-Catalyzed sp2/sp3 Diborylation of 1-Chloro-1-Trifluoromethylalkenes;ACS Central Science;2022-07-20
4. Copper-Catalyzed Ring-Opening Defluoroborylation of gem-Difluorinated Cyclobutenes: A General Route to Bifunctional 1,3-Dienes and Their Applications;Organic Letters;2022-03-03
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