An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

Author:

Nimax Patrick R.1234,Zoller Florian1234,Blockhaus Tobias1234,Küblböck Teresa1234,Fattakhova-Rohlfing Dina56784,Sünkel Karlheinz1234ORCID

Affiliation:

1. Department Chemistry

2. Ludwig-Maximilians-University Munich

3. 81377 Munich

4. Germany

5. Electrochemical Storage Department

6. Institut für Energie- und Klimaforschung: Werkstoffsynthese und Herstellungsverfahren (IEK-1)

7. Forschungszentrum Jülich GmbH Wilhelm-Johnen-Straße

8. 52425 Juelich

Abstract

Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl2with Ag[C5(CN)4(NH2)] and recrystallization in MeOH was performed in sunlight.

Funder

Ludwig-Maximilians-Universität München

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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