Ca2GeB2O7 and Ca1.78Cd0.22GeB2O7: two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou 350002
5. P. R. China
Abstract
Herein, two new borogermanates obtained by combining BO4 with the GeO4 tetrahedron exhibit short UV absorption edges and display second-harmonic generation signals.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI00678H
Reference62 articles.
1. Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response
2. High-Temperature, High-Pressure Hydrothermal Synthesis of Ba3[B6O10(OH)2](CO3) and Ba6[B12O21(OH)2](CO3)2, Two Barium Borate Carbonates with 2D Layer and 3D Framework Structures
3. A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units
4. Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal
5. Beryllium‐Free β‐Rb 2 Al 2 B 2 O 7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe 2 BO 3 F 2
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