Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy-Reference-Cited by-同舟云学术

Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy

Published:2022 Issue: Volume:238 Page:645-664
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Savee John D.¹,Sztáray Bálint²^ORCID,Hemberger Patrick³^ORCID,Zádor Judit¹^ORCID,Bodi Andras³^ORCID,Osborn David L.¹^ORCID

Affiliation:

1. Combustion Research Facility, Sandia National Laboratories, Mailstop 9055, Livermore, California, 94551, USA

2. Department of Chemistry, University of the Pacific, Stockton, California, USA

3. Laboratory for Synchrotron Radiation and Femtochemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland

Abstract

The unimolecular isomerisation of the propargyl + propargyl “head-to-head” adduct, 1,5-hexadiyne to fulvene and benzene via 3,4-dimethylenecyclobut-1-ene (all C6H6) was studied in the high-pressure limit by threshold photoelectron spectroscopy.

Funder

Bundesamt für Energie

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D2FD00028H

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