Spectroscopic study of ionic liquid adsorption from solution onto gold-Reference-Cited by-同舟云学术

Spectroscopic study of ionic liquid adsorption from solution onto gold

Published:2015 Issue:6 Volume:17 Page:4199-4209
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Beattie David A.¹²³⁴,Harmer-Bassell Sarah L.⁵⁶⁴,Ho Tracey T. M.¹²³⁴,Krasowska Marta¹²³⁴,Ralston John¹²³⁴,Sellapperumage Pasindu M. F.¹²³⁴,Wąsik Patryk¹²³⁴

Affiliation:

1. The Ian Wark Research Institute

2. University of South Australia

3. Adelaide

4. Australia

5. School of Chemical and Physical Sciences

6. The Flinders University of South Australia

Abstract

HMIM NTf₂ adsorbs on gold from ethanol to form a patchy bilayer. ‘Bound’ anion (filled anion) and ‘bound’ cation (filled blue) sit underneath a layer of cation (empty blue) and anion (empty orange). The IL regions are separated by oxidised gold (darker colour).

Funder

Swiss National Science Foundation

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05558F

Reference61 articles.

1. Ionic liquid lubricants: designed chemistry for engineering applications

2. A comparison of phosphorus and fluorine containing IL lubricants for steel on aluminium