Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex-Reference-Cited by-同舟云学术

Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex

Published:2022 Issue:15 Volume:12 Page:4753-4762
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Narjinari Himani¹,Tanwar Niharika²,Kathuria Lakshay¹,Jasra Raksh Vir²³,Kumar Akshai¹²⁴^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati – 781039, Assam, India

2. Centre for Nanotechnology, Indian Institute of Technology Guwahati, Guwahati – 781039, Assam, India

3. Reliance Industries limited, R&D Centre, Vadodara Manufacturing Division, Vadodara, 391 346, Gujarat, India

4. Jyoti and Bhupat School of Health Sciences and Technology, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India

Abstract

β-Alkylation of alcohols has been efficiently accomplished using readily available 3d metal Cr under microwave conditions in air. Well-defined molecular Cr is involved with a KIE of 7.33 and insertion of α-alkylated ketone into Cr–H bond as the RDS.

Funder

Science and Engineering Research Board

Ministry of Electronics and Information technology

Ministry of Education, India

Indian Council of Medical Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00759B

Reference111 articles.