Acyclic diaminocarbene-based Thiele, Chichibabin, and Müller hydrocarbons
Author:
Affiliation:
1. Tata Institute of Fundamental Research Hyderabad
2. Hyderabad-500046
3. India
4. Universität Stuttgart
5. Fakultät Chemie
6. Lehrstuhl für Anorganische Koordinationschemie
7. Institut für Anorganische Chemie
8. Stuttgart
Abstract
We report the synthesis of acyclic diaminocarbene (ADC)-scaffold based Thiele, Chichibabin, and Müller hydrocarbons. Studies support that the singlet-triplet energy gap depends on the π-conjugated spacer between the ADC scaffolds.
Funder
Department of Atomic Energy, Government of India
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03622F
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