Bifunctional Au–Sn-SiO2 catalysts promote the direct upgrading of glycerol to methyl lactate

Author:

Van der Verren Margot1ORCID,Corrias Anna2ORCID,Vykoukal Vit3,Styskalik Ales3,Aprile Carmela4,Debecker Damien P.1ORCID

Affiliation:

1. Institute of Condensed Matter and Nanoscience (IMCN), UCLouvain, Place Louis Pasteur 1, 1348 Louvain-La-Neuve, Belgium

2. University of Kent, School of Chemistry and Forensic Science, Ingram Building, Canterbury CT2 NH, UK

3. Masaryk University, Department of Chemistry, Kotlarska 2, CZ-61137 Brno, Czech Republic

4. Université de Namur, Unit of Nanomaterial Chemistry, Department of Chemistry, Namur 5000, Belgium

Abstract

Direct preparation of bifunctional catalysts featuring both dispersed Au nanoparticles and inserted Sn species, to catalyze effectively the cascade reaction of glycerol to methyl lactate; active site proximity ensures rapid substrate channeling and boosts selectivity and yield.

Funder

European Regional Development Fund

Fonds De La Recherche Scientifique - FNRS

Fondation Francqui - Stichting

Diamond Light Source

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

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