Molecular rotation induced giant, anisotropic negative thermal expansion in a hydrogen-bonded coordination framework-Reference-Cited by-同舟云学术

Molecular rotation induced giant, anisotropic negative thermal expansion in a hydrogen-bonded coordination framework

Published:2023 Issue:8 Volume:10 Page:2399-2403
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Meng Peng¹^ORCID,Brock Aidan¹,Wang Xiaodong²^ORCID,Wang Yuting¹,McMurtrie John¹^ORCID,Xu Jingsan¹^ORCID

Affiliation:

1. School of Chemistry and Physics & Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4000, Australia

2. Central Analytical Research Facility, Institute for Future Environments, Queensland University of Technology, Brisbane, QLD 4000, Australia

Abstract

We report a new supramolecular structure of cyanuric acid–melamine–zinc (CA–M–Zn) demonstrating unique molecular rotation induced negative thermal expansion along the c axis, accompanied by a significant decrease of β angle (−3.8%).

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02265F

Reference36 articles.

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