Solution- and gas-phase behavior of decavanadate: implications for mass spectrometric analysis of redox-active polyoxidometalates-Reference-Cited by-同舟云学术

Solution- and gas-phase behavior of decavanadate: implications for mass spectrometric analysis of redox-active polyoxidometalates

Published:2022 Issue:7 Volume:9 Page:1556-1564
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Favre Daniel¹,Bobst Cedric E.¹,Eyles Stephen J.²^ORCID,Murakami Heide³^ORCID,Crans Debbie C.³^ORCID,Kaltashov Igor A.¹^ORCID

Affiliation:

1. Departments of Chemistry, University of Massachusetts-Amherst, Amherst, MA, USA

2. Biochemistry and Molecular Biology, University of Massachusetts-Amherst, Amherst, MA, USA

3. Department of Chemistry, Colorado State University, Ft. Collins, CO, USA

Abstract

Analysis of decavanadate with high resolution mass spectrometry coupled with ion exclusion chromatography reveals naturally occurring partially reduced species in solution and novel gas-phase ion fragmentation pathways.

Funder

National Institute of General Medical Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D1QI01618K

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