ortho-Ethynyl group assisted regioselective and diastereoselective [2 + 2] cross-photocycloaddition of alkenes under photocatalyst-, additive-, and solvent-free conditions-Reference-Cited by-同舟云学术

ortho-Ethynyl group assisted regioselective and diastereoselective [2 + 2] cross-photocycloaddition of alkenes under photocatalyst-, additive-, and solvent-free conditions

Published:2021 Issue:20 Volume:8 Page:5872-5887
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xie Xiaofei¹²,Pan Hong²,Zhou Tai-Ping³,Han Man-Yi⁴^ORCID,Wang Lei¹²⁴^ORCID,Geng Xiao¹,Ma Yongmin¹,Liao Rong-Zhen³^ORCID,Wang Zhi-Ming¹^ORCID,Yang Jianguo¹,Li Pinhua²⁴^ORCID

Affiliation:

1. Advanced Research Institute and Department of Chemistry, Taizhou University, Taizhou, Zhejiang 318000, P. R. China

2. Key Laboratory of Green and Precise Synthetic Chemistry, Ministry of Education, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China

3. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, P. R. China

4. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, P. R. China

Abstract

A highly regioselective and diastereoselective [2 + 2]-cross-photocycloaddition between electron-poor and electron-rich/electron-neutral alkenes under visible-light irradiation without a photocatalyst, additive and solvent was developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01017D

Reference42 articles.

1. S.Kobayashi and K. A.Jørgensen , Cycloaddition reactions in organic synthesis , Wiley-VCH Verlag GmbH , Weinheim, Germany , 2001

2. N.Nishiwaki , Methods and applications of cycloaddition reactions in organic syntheses , John Wiley and Sons, Inc. Hoboken , New Jersey, USA , 2014

3. Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions