Electrostatic repulsion-controlled regioselectivity in nitrene-mediated allylic C–H amidations-Reference-Cited by-同舟云学术

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Electrostatic repulsion-controlled regioselectivity in nitrene-mediated allylic C–H amidations

Published:2021 Issue:21 Volume:8 Page:6038-6047
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Huang Fang¹^ORCID,Tian Xiaoxiao¹,Hou Fangao¹,Xu Yaping¹,Lu Gang²^ORCID

Affiliation:

1. College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong 250014, China

2. School of Chemistry and Chemical Engineering, Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, Shandong 250100, China

Abstract

The difference of repulsive electrostatic interactions between nitrene N and allyl carbon atoms is the dominant factor affecting the regioselectivity in metal nitrenoid-catalyzed allylic C–H amidations.

Funder

Taishan Scholar Foundation of Shandong Province

Shandong University

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01018B

Reference65 articles.

1. Catalytic C–H amination: the stereoselectivity issue

2. Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

3. Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

4. Transition-Metal-Mediated Direct C–H Amination of Hydrocarbons with Amine Reactants: The Most Desirable but Challenging C–N Bond-Formation Approach

5. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

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