Catalytic asymmetric construction of bridged bicyclo[<i>m</i>.3.1] rings using an intramolecular Diels

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Catalytic asymmetric construction of bridged bicyclo[m.3.1] rings using an intramolecular Diels–Alder reaction

Published:2024 Issue:71 Volume:60 Page:9570-9573
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Kai¹,Zhao Zhengxing¹,Qin Wenling¹^ORCID,Liu Yidong¹^ORCID,Yan Hailong²¹^ORCID

Affiliation:

1. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences, Chongqing University, Chongqing, 401331, P. R. China

2. Chongqing University FuLing Hospital, Chongqing University, Chongqing 408000, P. R. China

Abstract

An unconventional enantioselective intramolecular Diels–Alder (IMDA) reaction with vinyl branched vinylidene ortho-quinone methide (VQM).

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Natural Science Foundation of Chongqing Municipality

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02850C

Reference35 articles.

1. Approaches to the synthesis of ingenol

2. The Art of Innovation in Organic Chemistry: Synthetic Efforts toward the Phomoidrides

3. Synthetic Studies Inspired by Vinigrol

4. Synthetic efforts toward [3.3.1] bridged bicyclic phloroglucinol natural products

5. Total Synthesis of Natural Products with Bridged Bicyclo[m.n.1] Ring Systems via Type II [5 + 2] Cycloaddition

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